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1.
典型地区农用地污染调查及风险管控标准探讨 总被引:2,自引:0,他引:2
针对《土壤污染风险管控标准——农用地土壤污染风险管控标准》(GB 15618—2018),提出以土壤中全量浓度筛选值和管控值作为衡量农用地土壤污染风险管控的标准,对湖南省部分稻田农用地土壤及点对点稻米样品中镉、铅、砷、汞的总量和有效态浓度及稻米中含量进行监测,根据重金属总量浓度分为低风险、中风险、高风险3组。结果显示:(1)土壤及稻米中镉含量基本为随着风险级别的升高而增加,铅、砷在土壤和稻米中含量无规律性结果,汞监测结果均为未检出。(2)低风险组稻米镉超标率为12. 0%,高风险组稻米镉达标率为33. 3%,表明利用总量浓度对农用地土壤潜在风险进行分组存在一定的局限性。(3)依据4种重金属在土壤中总量及稻米(早稻)中含量情况,对风险级别进行调整并综合判断:有58个样品为低风险组,占样品总数的68. 2%,超标率为零;有15个样品为中风险组,占样品总数的17. 7%,超标率为80. 0%;有12个样品为高风险组,占样品总数的14. 1%,超标率为100. 0%。调整后评价结果与上述标准的划分目标更接近,能够提高上述标准的准确性和实用性。 相似文献
2.
3.
重金属生物有效性是评估重金属元素迁移性、生物可利用性和生态影响的关键参数。薄膜扩散梯度技术(DGT)是一种原位被动采样技术,因其具有原位富集性、形态选择性,可提供被监测物质在监测时间段内的平均浓度等优点,可作为生物对重金属摄取的模拟替代物对环境介质中重金属的生物可利用度进行预测,已被广泛应用于环境介质中重金属生物有效性的测定。研究主要介绍了DGT技术的原理、组成和特点,评述了其近年来在水体、土壤、沉积物中重金属生物有效态应用方面的新进展,提出了DGT技术未来要提高抗生物污染能力及寻找可与DGT技术联用的相关技术的观点。 相似文献
4.
The effects of Cu2+, Cd2+, and Ni2+ at low and high concentrations (0.025 and 0.25 mg/ml) on the accumulation capacity, the state of the pigment complex, and photosynthesis rate have been studied in model experiments with three floating hydrophytes (Hydrocharis morsus-ranae L., Lemna gibba L., and Potamogeton natans L.) and four submerged hydrophytes (Elodea canadensis Michx., Lemna trisulka L., Ceratophyllum demersum L., and Potamogeton lucens L.). Copper and cadmium are especially toxic at the concentrations studied. The effect of Cu2+ was the strongest in hydatophytes, and the effect of Cd2+, in pleustophytes. It is hypothesized that the differences between hydrophytes with respect to accumulation of metals and decrease in photosynthesis rate may cause predominant elimination of submerged species. Therefore, changes in the species structure of hydrophyte communities may be expected in waters polluted with metals. 相似文献
5.
Heavy metal accumulation in Littoraria scabra along polluted and pristine mangrove areas of Tanzania
The periwinkle Littoraria scabra was collected at polluted and pristine mangrove sites along the Tanzanian coastline, including Msimbazi, Mbweni (i.e. Dar es Salaam) and Kisakasaka, Nyamanzi and Maruhubi (i.e. Zanzibar). Periwinkles were morphologically characterized, sexed and their heavy metal content was determined using ICP-MS. Analysis revealed that L. scabra from polluted areas contained higher soft tissue heavy metal levels, were significantly smaller and weighed less compared to their conspecifics from the unpolluted mangroves. The current morphological observations may be explained in terms of growth and/or mortality rate differences between the polluted and non-polluted sites. Although a variety of stressors may account for these adverse morphological patterns, our data suggest a close relationship with the soft tissue heavy metal content. Compared to soft tissue heavy metal levels that were measured in L. scabra along the same area in 1998, most metals, except for arsenic, chromium and iron have decreased dramatically. 相似文献
6.
The feasibility of using U.K. coal-fired power station waste materials for artificial reef production is being examined. in June, 1989, an experimental artificial reef was constructed in Poole Bay, off the central south coast of the U.K., using three different mixtures of pulverised fuel ash (PFA), flue gas desulphurisation (FGD) gypsum and slurry, stabilized with cement and formed into blocks. Fifty tonnes of 40 × 20 × 20 cm blocks were formed into eight conical reef units replicating three different PFA/gypsum mixtures and one concrete control. the reef structure is 10m below chart datum on a flat sandy sea-bed.
Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.
The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.
An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus). 相似文献
Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.
The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.
An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus). 相似文献
7.
Mark Walker W. Douglass Shaw Marnee Benson 《Journal of the American Water Resources Association》2006,42(5):1363-1370
ABSTRACT: Churchill County, Nevada, has approximately 23,000 residents, among whom an estimated 13,500 relied on private wells for water supply in 2002. This study examined exposure to arsenic in water supplies among residents with private domestic wells and factors related to householder choice to consume tap water. It compared opinions and concerns about water quality with consumption habits and observed concentrations from tap water samples. The results from 351 households indicated that a majority (75 percent) of respondents consumed tap water and that a minority (38 percent) applied treatment. Approximately 66 percent of those who consumed tap water were exposed to concentrations of arsenic that exceeded 10 ppb. Water consumption was related to application of treatment. Among 98 respondents who were not at all concerned about the health effects of aqueous arsenic, 59 (60 percent) reported consuming tap water with concentrations of arsenic exceeding 10 ppb. Conversely, among 86 respondents who were highly concerned about arsenic, 33 (37 percent) consumed tap water with concentrations of arsenic exceeding 10 ppb. Results from a national sampling effort showed that 620 of 5,304 private wells sampled (11.7 percent) had arsenic concentrations above 10 ppb. The paradox of awareness of arsenic in water supplies coupled with consumption of aqueous arsenic in concentrations greater than 10 ppb may be common in other parts of the nation. Enhanced educational efforts, especially related to tap water sampling and explanations of efficacy of available treatment, may be useful means of reducing exposure through private water supplies. 相似文献
8.
María L. Pignata Martha S. Cañas Hebe A. Carreras Liliana Orellana 《Environmental management》1997,21(5):793-801
Ligustrum lucidum Ait. f. tricolor (Rehd.) Rehd. in relation to atmospheric pollutants in Córdoba city, Argentina. The study area receives
regional pollutants and was categorized taking into account traffic level, industrial density, type of industry, location
of the sample point in relation to the street corner, treeless condition, and topographic level. Dried weight/fresh weight
ratio (DW/FW) and specific leaf area (SLA) were calculated, and concentrations of chlorophylls, carotenoids, total sulfur,
soluble proteins, malondialdehyde (MDA), and hydroperoxy conjugated dienes (HPCD) were determined in leaf samples. Sulfur
content correlates positively with traffic density and SLA correlates negatively with some combinations of the categorical
variables; MDA correlates positively with topographic level and total protein concentration correlates negatively with treeless
condition. On the basis of our results, traffic, location of trees, type of industry, situation of a tree with respect to
others, and topographic level are the environmental variables to bear in mind when selecting analogous sampling points in
a passive monitoring program. An approximation to predict tree injury may be obtained by measuring DW/FW ratio, proteins,
pigments, HPCD, and MDA as they are responsible for the major variability of data. 相似文献
9.
三峡库区中低产土壤重金属含量及其与小麦吸收的关系 总被引:3,自引:0,他引:3
三峡库区中低产土壤的Hg,As,Cr,Pb,Cu五个重金属含量(除渝北区外),均在国家土壤环境质量标准内,属自然背景值一级标准。Cd和Zn高于全国土壤中的平均含量和背景值含量,属二级标准。土壤的重金属含量与土壤母质类型,pH值,阳离子交换量,有机质,无定形铁和物理性粘粒有关,同时存在一定的地域分布。重庆近郊的土壤所有重金属含量相对较高。土壤重金属的可给态或有效性含量极低,锌和铜不是过量,而是不足。小麦籽粒中As,Cr,Pb,Zn,Cu含量低于国家食品对重金属限量标准和小麦籽粒背景值标准,Hg,Cd含量高于国家规定标准。籽粒中的Cu,Zn含量是小麦茎叶中的2.0-2.2倍,而茎叶中的Hg,Pb,As,Cr,Cd含量明显高于籽粒。 相似文献
10.
长江口没冒沙演变过程及其对水库工程的响应 总被引:2,自引:0,他引:2
研究南槽没冒沙演变规律,可以为筑库引淡蓄水工程建设提供科学依据。根据该海区近百年来各个时期的海图和20年来的实测水文泥沙等资料以及2003、2004年的现场观测数据,探讨了没冒沙的形成及形成后的演变过程。研究表明:没冒沙的形成和发育经历了局部边滩冲刷、边滩沙嘴发育和沙脊形成3个阶段;近半个世纪来,沙体中轴位置在稳定强劲的涨落潮流作用下呈现出西北—东南走向的良好的稳定性,具有潮流脊性质。而蓄淡水库工程建设将有可能使南槽成为适应进出水沙量的新型河槽。 相似文献